WebChemistry. Chemistry questions and answers. [Co (H2O)6]3+ is a strong oxidizing agent that will oxidize water, but [Co (NH3)6]3+ is stable in aqueous solution. Rationalize this observation by comparing the difference in LFSE for each pair of oxidized and reduced complexes (that is, the differences in LFSE between [Co (H2O)6]3+ and [Co (H2O)6]2 ... WebJan 28, 2024 · Another method to determine the spin of a complex is to look at its field strength and the wavelength of color it absorbs. If the field is strong, it will have few unpaired electrons and thus low spin. If the field is weak, it will have more unpaired electrons and … Description of d-Orbitals . To understand CFT, one must understand the … The Aufbau principle originates from the Pauli’s exclusion principle which …
Chem 27 Ch.19 questions Flashcards Quizlet
WebComplex A0 (cm—1) B ' (Om—1) [Co(NH3)6]2+ 10200 885 [Co(bipy)3]2+ 12670 791 (i) What information is conveyed by the Racah parameter, B? Use the data to assess the relative covalency of the metal—ligand bonding in the given complexes. ... which of the following complexes is high-spin and which is low-spin. Which of these complexes is … WebThis is a question that the crystal field theory cannot answer because of its inherent shortcomings. The crystal field theory assumes point-type charges approaching the central metal from the coordinate axes leading to the destabilisation of those $\mathrm d$ orbitals that do not feature a nodal plane in the coordinate axes: $\mathrm{d}_{x^2-y^2}$ and … ma03 oa 06 material concreto
Is [Co (NH₃)₄Cl₂]Cl paramagnetic or diamagnetic?
Web(2) This part question concerns the electronic absorption spectrum of [C0(H20)6]2+. The Orgel diagram for d 2' d 3, d id 8 high-spin octahedral or tetrahedral ions is provided below. (i) Sketch, in terms of d orbital splitting, all the possible ground state configurations of [C0(H20)6]2+. Hence deduce the ground state term of this complex ion. WebFor the low-spin complex [Co(en)(NH3)Cl2]ClO4, identify the following: (a) the coordination number of cobalt. (b) the coordination geometry for cobalt. (c) the oxidation number of cobalt. (d) the number of unpaired electrons. (e) whether the … WebWhat kind of ligand is NH3? Ammonia (NH3) is known to be a strong field ligand since the donor atom in this case is nitrogen.. Is H2O a pi donor ligand? o H2O is strong σ-donor and weak π-donor ligand, hence it is often classed as a σ-donor ligand. ... o compared to O2– which has 2 strong π-donor interactions, H2O has one poor π-donor FO (b1) and one … m9 scene\u0027s